Canonical partition function for the hydrogen atom via the Coulomb propagator
نویسندگان
چکیده
منابع مشابه
Canonical partition function for the hydrogen atom via the Coulomb propagator
The electronic partition function for the hydrogen atom is derived by integration over the recently-available Coulomb propagator. This provides a resolution to an old paradox in statistical mechanics: the apparent divergence of the hydrogen partition function. Electronic excitation does not contribute significantly to the standard-state partition function until temperatures of the order of 5000...
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ژورنال
عنوان ژورنال: Journal of Mathematical Physics
سال: 1995
ISSN: 0022-2488,1089-7658
DOI: 10.1063/1.531115